Online resource for learning Chinese
MyLanguages.org Chinese has a set of resources available for total beginner learners of Chinese.
Covers Chinese basics
These resources include information about the Chinese alphabet, adjectives, adverbs, articles, gender, nouns, numbers, phrases, singular and plural, pronouns, verbs, vocabulary, translation, dictionary, video, audio, reading and transliteration.
Also included is a simple Chinese phrasebook.
Free to start learning Chinese
This resource allows you to get started with Chinese and includes audio recordings of the vocabulary terms.
It's totally free:)